Why can a monobath give good results on films with very different normal development times?

Asked 4/23/2020

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I’m seeing surprisingly good negatives from a commercial monobath, even when I process different films together for the same time—for example, the same brand’s ISO 100 and ISO 400 films in one tank. In conventional development, those films would normally need quite different times, and giving the ISO 100 film the ISO 400 time would usually act like a push. I understand that a monobath works by development and fixing happening at the same time, with fixing eventually cutting development short. So why can a modern monobath still produce normal-looking negatives across films that would ordinarily require very different development times?

Originally by Photography Stack Exchange contributor. Source · Licensed CC BY-SA 4.0

Photography Stack Exchange contributor

6y ago

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What's commonly left out here is that faster films, generally, have larger halide grains. This is why, for instance, Tri-X has always had a longer development time (same developer and temperature) than Plus-X.

And this same factor means faster films also take longer to fix -- a larger halide grain takes longer to dissolve, from the surface inward. This means that larger grains will have more time to develop in a monobath before the fixing action removes the halide.

Monobaths (especially modern ones based on a rapid fixer formula) use very fast-acting developers: fast enough that there would be risk of uneven development in a tank process (the usual rule of thumb is to make three minutes your minimum). This is offset by the rapid fixing, however, so uneven development isn't a problem with monobaths -- the fixing starts at the same time as development, and if this time varies as the tank fills, it doesn't matter because each square millimeter of film will start both processes together, and fixing regulates development.

In the end, what makes modern monobaths work equally well with, say, Ilford Pan F and Kodak T-Max P3200 is that the longer it takes to develop, the longer it'll take to fix.

Originally by user89902. Source · Licensed CC BY-SA 4.0

user89902

6y ago

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AI Answer

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Because in a monobath, development time is not controlled the same way it is in a normal developer-only process.

A key factor is grain size. Faster films generally use larger silver halide grains, and those larger grains take longer to fix because the fixer has to dissolve them from the outside inward. That gives the faster film more time to develop before fixing stops the process.

So although an ISO 400 film may need longer in a conventional developer, it also tends to resist fixing longer in a monobath, which helps balance things out. Slower films with smaller grains fix sooner, so their development is cut off earlier.

Modern monobaths also use very active developers, often paired with rapid fixer chemistry. The developer works quickly, while the fixer limits total development. That combination makes the process somewhat self-regulating across films with different normal development times.

So the monobath is not really “ignoring” the differences between films—it’s using the fact that films that develop differently also tend to fix differently.

UniqueBot

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6y ago

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