Can a floating paraffin-oil lid help preserve darkroom chemicals?
Asked 7/29/2019
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I’ve seen floating lids with a paraffin-oil seal used on wine tanks to reduce air contact as the liquid level drops. Could the same idea work for storing photographic chemicals in a darkroom? I’m specifically asking whether a floating lid and/or paraffin oil layer is suitable for reusable photo chemistry such as developer, stop bath, fixer, and wash aid, and whether the oil is inert enough for this purpose.
Originally by Photography Stack Exchange contributor. Source · Licensed CC BY-SA 4.0
Photography Stack Exchange contributor
6y ago
2 Answers
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Adding a top coat of hot liquid paraffin is in the "how to do it books" for storage of photo chemicals. I did this 50+ years ago in my home darkroom in the water heater closet. Better is adding clean marbles or using plastic storage bottles and squeezing the air out. I have used nitrogen filled bottles. I have used nitrogen filled storage tanks. I have used floating lids of paraffin. Common was polyethylene stars that floated on top in storage vats. The small star shaped hollow floats interlocked and thus reduce the air liquid junction. Many 4x5 and 8x10 hard rubber processing tanks came with hard rubber floating lids. Lots of ways to reduce evaporation and oxidation. Developer formulas all feature a preservative that retards aerial oxidation and reacts with oxidized developing agents to neutralize staining agents. Many of the other chemicals of the process also feature preservatives.
From the comments:
Please explain why the use of marbles/squeeze bottle to get the liquid up to the bottle spout (minimal oxidizing surface area) is better than a lid that brings the oxidizing surface area to 0. I could take a guess at it but I'd like to hear your perspective on it.
Protection against aerial oxidation can be a mix of things depending on the type of container and type of fluid. My mother used paraffin when canning fruit and vegetables. I used paraffin when I stored chemicals in canning jars. Marbles displace liquid bringing the fluid to the top of the bottle neck of glass storage bottles. Plastic bottles leach plasticizer depending on type of plastic and type of fluid. Bottom line, many ways to accomplish this task including switching to dry photography.
Originally by user44949. Source · Licensed CC BY-SA 4.0
user44949
6y ago
0
Generated from our catalog & community — verify before relying on it.
Yes—this approach has been used for photographic chemicals. A floating lid and/or a thin paraffin oil layer can reduce the liquid-to-air contact, which helps limit oxidation and evaporation during storage. Older darkroom practice included paraffin on top of stored chemistry, floating lids in processing tanks, and floating plastic covers for larger vats.
That said, it’s mainly useful where aerial oxidation is the concern, especially with developers. Traditional developer formulas already include preservatives to slow this process, so the paraffin method is an extra protective measure rather than a requirement. The provided answers support it as a workable darkroom storage technique, not as harmful by default.
Practical drawbacks still matter: it’s more awkward for repeatedly opening, pouring, and returning chemistry than ordinary bottles. For many home darkrooms, squeezing air from plastic bottles or displacing volume with clean marbles is simpler. But if your goal is specifically to minimize air exposure in partially full containers, a floating paraffin-oil seal is a legitimate, historically used method.
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