Only in a limited sense. From a single photo, you can crop to simulate a narrower field of view from the same camera position. That gives the framing of a longer lens, but not the look of stepping farther back.

The important point is that perspective is determined by camera position, not focal length. A wide lens doesn’t just “distort” arbitrarily; it records a very wide view and projects 3D space onto a 2D image. Once that’s done, missing information is gone.

So if you want the photo to look as if it were taken from farther away with a longer lens, post-processing cannot truly reconstruct that from one image. You would need 3D scene information, multiple images, or a full scene model. A simple perspective/affine transform won’t do it convincingly because it can’t reveal hidden surfaces or correct object relationships that depend on viewpoint.

You can sometimes reproject or correct lens/perspective issues slightly, but you cannot make a single wide-angle room photo fully truthful to a different viewpoint after the fact.