What UV light and chemistry are involved in cyanotype printing?
Asked 2/16/2016
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I understand the basic steps of making a cyanotype, but I’m specifically interested in the chemistry and light requirements behind the process. What chemical change happens during exposure, and what kind of light drives it? For example, is cyanotype mainly sensitive to UV, and if so, roughly what wavelength range is used? Does the strength of the UV source matter, and why can cyanotypes usually be handled safely under normal indoor lighting?
Originally by Photography Stack Exchange contributor. Source · Licensed CC BY-SA 4.0
Photography Stack Exchange contributor
10y ago
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The process is reduction of iron Fe(III) to Fe(II), which then forms ferric ferrocyanide (Prussian blue). It is accomplished by UV rays.
The UV is the fun part: you can safely work the solution under most indoor lightning (which has no UV) and then expose under sunlight (which has UV). The process works in the near visible UV range = 350 - 400 nm, so you can expose your negative under glass.
The process requires light of similar wavelength as acrylic UV gels used in the art nails industry, and some practitioners use a manicure UV curing lamp instead of more traditional sunshine.
The only negative of the process is that requires a lot of UV light to work, and so it is practical only for 1:1 copying (negative and positive of the same size). This is can be overcome by printing the negative digitally on a transparent foil of the required size.
Analogue purists either shoot their negatives on (ultra) large format sheet film (8×10 and bigger) or enlarge their negatives in darkroom. Both requires serious dedication and is best left to advanced users.
This ease of work, together with simple fixing - just a rinse with water to wash away leftover Fe(III) salts - and relatively harmless materials used (compared to other photo processes) makes Cyanotype process great for beginners and even older children.
Originally by user62463. Source · Licensed CC BY-SA 4.0
user62463
9y ago
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Generated from our catalog & community — verify before relying on it.
Cyanotype works by a light-driven reduction of iron: ferric iron, Fe(III), is reduced to ferrous iron, Fe(II), and this then leads to formation of ferric ferrocyanide, also known as Prussian blue.
The process is mainly sensitive to near-UV light, roughly in the 350–400 nm range. That’s why cyanotypes can often be prepared and handled under typical indoor lighting with little issue: many indoor light sources emit very little UV. Sunlight works well because it contains enough UV in that range.
Exposure strength does matter in practice. Cyanotype generally needs a fairly strong UV source, which is why sunlight is traditional and why some people also use UV lamps such as manicure curing lamps with similar output. Because it needs substantial UV exposure, cyanotype is most practical as a contact-printing process, where the negative is the same size as the final print.
A useful consequence of this wavelength range is that exposure can be done under glass, since the needed near-UV can pass through ordinary glass well enough for the process to work.
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